Using technical sulfur as a structuring additive for mineral binders based on calcium sulfate

    Grigorij I. Yakovlev Affiliation
    ; Irina S. Polyanskih Affiliation
    ; Anastasia F. Gordina Affiliation
    ; Aleksandr N. Gumeniuk Affiliation


The article discusses physical and chemical characteristics of producing effective materials based on calcium sulfate dihydrate, the pretreated waste of man-made production being added at the stage of mixing the air binder. The high degree of consumption of exhaustible natural resources causes increased research activities in the field of application of industrial waste in construction. Using manmade waste, such as technical sulfur, as a modifier of the structure and properties of building materials is a significant step in solving environmental, resource, and economic problems. Industrial production of building materials today follows the principles of sustainable development and waste minimization by optimizing product formulations and reducing energy consumption required for their production. In addition, the improvement of quality and performance indicators of standardized products is relevant and sought-after. The need for efficient technologies for utilization of technical sulfur is due to large volumes of production and the environmental threat which accompanies the storage of its large volumes. Adding technical sulfur as a component of technological construction mixtures will create an alternative to the methods of utilization of this production waste. Physical and technical and physical and chemical properties of technical sulfur predetermine the possibility of its use, with certain additional treatment, as an effective modifier of the structure and properties of gypsum products. The results presented in the article prove the potential use of this production waste as an effective structure-forming additive, which has a positive effect on the physical and technical parameters of calcium sulfate-based materials.

First published online 10 February 2020

Keyword : polymerization, man made sulphur, gypsum, structure formation, thermoplastic additive, surface working, waste product, properties improvement

How to Cite
Yakovlev, G. I., Polyanskih, I. S., Gordina, A. F., & Gumeniuk, A. N. (2019). Using technical sulfur as a structuring additive for mineral binders based on calcium sulfate. Engineering Structures and Technologies, 11(3), 95-100.
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Dec 31, 2019
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Al-Hadithi, A. I., Al-Saleem, H. I., & Ikzer, B. G. (1987). Evaluation of properties of bricks impregnated with sulphur. Materials and Structures, 20(4), 265–269.

Bazhenov, Y. M. (1983). Concrete polymers. Stroyizdat.

Beliankin, D. S., Ivanov, B. V., & Lapin, V. V. (1952). Petrography of technical stone. Publishing office AN USSR.

Berg, L. G. (1969). Introduction to thermography. The science.

Berg, L. G. (1956). Gypsum and its dehydration products. In A. V. Astrova (Ed.), Academician D. S. Beliankin selected works (Т. 1, pp. 321–330). Publishing office AN USSR.

Bormotov, A. N., Proshin, I. A., & Korolev, E. V. (2010). Simulation of destruction and a method for predicting the durability of composite materials. Bulletin of Izhevsk State Technical University, (4), 113–118.

Ciak, N., & Harasymiuk, J. (2013). Sulphur concrete’s technology and its application to the building industry. Technical Sciences, 16(4), 323–331.

Chaudhuri, R. G., & Paria, R. (2010) Synthesis of sulphur nanoparticles in aqueous surfactant solutions. Journal of Colloid and Interface Science, 343(2), 439–446.

Fedotov, K. M. (1956). On the issue of dehydration of gypsum. In A. V. Astrova (Ed.), Academician D. S. Beliankin selected works (Т. 1, pp. 238–244). Publishing office AN USSR.

Gedik, A., & Lav, A. H. (2016). Analytical, morphological, and rheological behavior of sulphur-extended-binder. Canandian Journal of Civil Engineering, 43(6), 532–541.

Gamara, T. B., & Pablo, A. A. (1980). Research and development on the utilization of sulfur for low-cost building materials. NSDB Technology Journal, (1), 34–41.

Gregor, R., & Hackl, A. (1978). A new approach to sulfur concrete. In D. J. Borne (Ed.), II New Uses Sulfur (pp. 54–78). ACS Publications.

Gemot, M. (1978). Schwefelbeton – experimente mit einem neuen Baustof. Deutch Bauzietse-hrift, (10), 1385–1388.

GOST 127.1-93. Sera tehnicheskaja. Tehnicheskie uslovija [Sulfur technical specifications] (in Russian).

Korolev, E. V., Kiselev, D. G., Proshina, N. A., & Albakasov, A. I. (2011). Thermophysical properties of sulfur building materials. Vestnik MGSU, 6(8), 249–253.

Kuntsevich, O. V., & Petrenas, I. I. (1976). The study of the adhesion of cement-polymer composites with mineral aggregates. LIIZhT.

La Mer, V. K., & Kenyon, A. S. (1947). Kinetics of the mono dispersed sulphur solu-tion from thiosulphate and acid. Journal of Colloid Science, 2(2), 257–264.

Menkovskiy, M. A., & Yavorsky, V. T. (1985). Sulfur technology. Chemistry.

Mikhailov, K. V., Patuoev, V. V., & Kreis, R. (1989). Polymer concrete and constructions based on them. Stroiizdat.

Vernigorova, V. N., Korolev, E. V., Sokolova, U. A., & Sadenko, S. M. (2009). Physico-chemical methods for studying the properties of building composite materials. Paleotip.

Petrukhina, N. P. (2016). Quality passport No. 448Н. Sulfur technical gas granulated, variety 9998.

Proshin, A. P., Danilov, A. M., Korolev, E. V., & Smirnov, V. A. (2002). Dynamic models in the study of cluster formation in composite materials. Limit systems. News of Higher Educational Institutions. Construction, (3), 32–38.

Polyasnkikh, I. S., Yakovlev, G. I., Gordina, A. F., Gumenyuk, A. N., Drohitka, R., & Urhanova, L. A. (2018, September). Compositions based on industrial sulfur sol for gypsum materials. In Ibausil. 20. Internationale Baustofftagung (pp. 569–575). Weimar.

Panfilov, D. V. (2004). Dispersion-reinforced construction composites based on polybutadiene oligomer (Abstract of the thesis of the candidate of technical sciences: 05.23.05). Voronezh.

Rayne, C. (1951). Sulfuric composite materials for power system. Indusry Engenier Chemie, (3), 2205.

Rivkin, S. L., & Aleksandrov, A. A. (1984). Termodinamicheskie svoystva vody i vodyanogo para [Thermodynamic properties of water and steam]: a handbook. Energoatomizdat. (in Russian).

Steudel, R. (2003). Liquid sulfur. In R. Steudel (Ed.), Toppics in current chemistry: Vol. 230. Elemental sulfur and sulfur-rich compounds I (pp. 81–116). Springer.

Sassi, M., & Gupta, A. K. (2008). Sulphur recovery from acid gas using the claus process and high temperature air combustion technology. American Journal of Environmental Sciences, 4(5), 502–511.

Sumio, S. (Ed.). (2004). Handbook of sol-gel science and technology: processing characterization and applications. Kluwer Accademic Publishers.

Santucci, L. E., Cambell, R. W., Woo Garlok. (1974) Patent No. 3997355. United States Patent and Trademark Office.

Tager, A. A. (2007). Physical chemistry of polymers. (4th ed.). Nauchnyi mir.